High Field Magneto-Conductivity Analysis of Bi2Se3 Single Crystal

We report the high field (up to 14Tesla) magneto-conductivity analysis of Bi2Se3 topological insulator grown via the self flux method. The detailed experimental investigations including crystal growth as well as the electrical, thermal and spectroscopic characterizations of the resultant Bi2Se3 single crystal are already reported by some of us. The current letter deals with high field magneto-conductivity analysis in terms of Hikami Larkin Nagaoka (HLN) model, which revealed that the electronic conduction is dominated by both surface states driven weak anti localization (WAL), as well the bulk WL (weak localization) states. Further, by applying the HLN equation we have extracted the fitting parameters i.e., phase coherence length and the pre-factor. The HLN equation exhibited values of [pre factor close to -1.0, indicating both WAL and WL contributions. On the other hand, the extracted phase coherence length is seen to decrease from 11.125 nm to 5.576 nm as the temperature is increased from 5K to 200K respectively. Summarily, the short letter discusses primarily the temperature dependent magneto-conductivity analysis of pristine Bi2Se3 single crystal by the HLN model.Comment: Letter to Editor MS: 10 pages including 3 Fig

Crystal Growth and Characterization of Bulk Sb2Te3Topological Insulator

The Sb2Te3 crystals are grown using the conventional self flux method via solid state reaction route, by melting constituent elements (Sb and Te) at high temperature (850 C), followed by slow cooling (2 C per hour).The weak anti localization (WAL) related low field (2 Tesla) magneto-conductance at low temperatures (2.5 K and 20 K) has been analysed and discussed using the Hikami- Larkin - Nagaoka (HLN) model. Summarily, the short letter reports an easy and versatile method for crystal growth of bulk Sb2Te3 topological insulator (TI) and its brief physical property characterization.Comment: 18 Pages Text + Figs: Accepted Mat. Res. Exp. (May 2018

High Field (up to 140kOe) Angle Dependent Magneto Transport of Bi2Te3 Single Crystals

We report the angle dependent high field (up to 140kOe) magneto transport of Bi2Te3 single crystals, a well-known topological insulator. The crystals were grown from melt of constituent elements via solid state reaction route by self-flux method. Details of crystal growth along with their brief characterization up to 5 Tesla applied field was reported by some of us recently [J. Magn. Mag. Mater. 428, 213 (2017)]. The angle dependence of the magneto-resistance (MR) of Bi2Te3 follows the cos Theta function i.e., MR is responsive, when the applied field is perpendicular (tilt angle Theta = o and/or 180) to the transport current. The low field (10 kOe) MR showed the signatures of weak anti localization (WAL) character with typical cusp near origin at 5 K. Further, the MR is linear right up to highest applied field of 140 kOe. The large positive MR are observed up to high temperatures and are above 250 and 150 percent at 140 kOe in perpendicular fields at 50 K and 100 K respectively. Heat capacity CP(T) measurements revealed the value of Debye temperature to be 135 K. ARPES (angle resolved photoemission spectroscopy) data clearly showed that the bulk Bi2Te3 single crystal consists of a single Dirac cone.Comment: 13 Pages text + Figs... Letter - Mat. Res. Ex

Hikami-Larkin-Nagaoka (HLN) treatment of the Magneto Conductivity of Bi2Te3 Topological Insulator

We report the magneto-conductivity analysis at different temperatures under magnetic field of up to 5Tesla of a well characterized Bi2Te3 crystal. Details of crystal growth and various physical properties including high linear magneto resistance are already reported by some of us. To elaborate upon the transport properties of Bi2Te3 crystal, the magneto conductivity is fitted to the known HLN (Hikami Larkin Nagaoka) equation and it is found that the conduction mechanism is dominated by both surface driven WAL (weak anti localization) and the bulk WL states. The value of HLN equation coefficient signifying the type of localization (WL, WAL or both WL and WAL) falls within the range of -0.5 to -1.5. In our case, the low field (0.25Tesla) fitting of studied crystal exhibited value close to -0.86 for studied temperatures of up to 50K, indicating both WAL and WL contributions. The phase coherence length is found to decrease from 98.266 to 40.314nm with increasing temperature. Summarily, the short letter reports the fact that bulk Bi2Te3 follows the HLN equation and quantitative analysis of the same facilitates to know the quality of studied crystal in terms of WAL to WL contributions and thus the surface to bulk conduction ratio.Comment: Short Letter MS 10 pages including 3 Figs: Letter J. Sup. & Novel Mag. (2018

Electrical, Thermal and Spectroscopic Characterization of Bulk Bi2Se3 Topological Insulator

We report electrical (angular magneto-resistance, and Hall), thermal (heat capacity) and spectroscopic (Raman, x-ray photo electron, angle resolved photo electron) characterization of bulk Bi2Se3 topological insulator, which is being is grown by self flux method through solid state reaction from high temperature (950C) melt and slow cooling (2C/hour) of constituent elements. Bi2Se3 exhibited metallic behaviour down to 5K. Magneto transport measurements revealed linear up to 400% and 30% MR at 5K under 14 Tesla field in perpendicular and parallel field direction respectively. We noticed that the magneto-resistance (MR) of Bi2Se3 is very sensitive to the angle of applied field. MR is maximum when the field is normal to the sample surface, while it is minimum when the field is parallel. Hall coefficient (RH) is seen nearly invariant with negative carrier sign down to 5K albeit having near periodic oscillations above 100K. Heat capacity (Cp) versus temperature plot is seen without any phase transitions down to 5K and is well fitted (Cp = gammaT + betaT3) at low temperature with calculated Debye temperature (ThetaD) value of 105.5K. Clear Raman peaks are seen at 72, 131 and 177 cm-1 corresponding to A1g1, Eg2 and A1g2 respectively. Though, two distinct asymmetric characteristic peak shapes are seen for Bi 4f7/2 and Bi 4f5/2, the Se 3d region is found to be broad displaying the overlapping of spin - orbit components of the same. Angle-resolved photoemission spectroscopy (ARPES) data of Bi2Se3 revealed distinctly the bulk conduction bands (BCB), surface state (SS), Dirac point (DP) and bulk valence bands (BVB) and 3D bulk conduction signatures are clearly seen. Summarily, host of physical properties for as grown Bi2Se3 crystal are reported here.Comment: 6 Pages Text + Figs; Comments Suggestions welcom

Unexplored photoluminescence from bulk and mechanically exfoliated few layers of Bi2Te3

We report the exotic photoluminescence (PL) behaviour of 3D topological insulator Bi2Te3 single crystals grown by customized self-flux method and mechanically exfoliated few layers (18 plus minus 2 nm)/thin flakes obtained by standard scotch tape method from as grown Bi2Te3 crystals.The experimental PL studies on bulk single crystal and mechanically exfoliated few layers of Bi2Te3 evidenced a broad red emission in the visible region. These findings are in good agreement with our theoretical results obtained using the ab initio density functional theory framework.Comment: Main MS (17 Pages text including 4 Figs): Suppl. info. (4 pages); Accepted Scientific Report

What type of leadership is more effective for managing change during force majeure? Achieving organizational effectiveness during the pandemic

Purpose – Leaders have been facing serious challenges in managing organizations during COVID-19, which has brought the need for implementing sudden technological change across the globe. Hence, it was important to identify effective leadership styles to successfully manage the transformational process during the period. Therefore, the current study aims to explore and compare the effectiveness of transformational and ethical leadership (EL) in terms of achieving organizational goals during COVID-19 in public and private sector organizations in Pakistan. Design/methodology/approach – Comparative research was carried out to find out the effectiveness of transformational and EL during and pre-COVID-19 in public and private sector organizations using the lens of social exchange theory. Data was collected from 214 respondents representing 67.6% of public and 32.4% of private sector organizations of Pakistan at two different points in time. Detailed comparative analyses were conducted in AMOS version 24 to assess the effectiveness of leadership styles before and during COVID-19 times. Findings – On the whole, transformational leadership (TL) was found to have a greater impact on organizational effectiveness (OE) in comparison with EL in both pre-and during COVID-19 situations. Moreover, the effectiveness of TL significantly increased and the same decreased for EL during COVID-19. Additional analyses indicated that TL was effective for the private sector and EL for public sector organizations during COVID-19. Research limitations/implications – The study has not considered the mediating mechanisms of employee motivation, engagement and performance in the relationship between transformational and EL styles and OE, which can be explored in the future. Practical implications – These results have important implications for private and public sector organizations and suggest that the adoption of a TL style will generate better results in the private sector and an EL style in public sector organizations to achieve OE in uncertain situations such as COVID-19. Social implications – The study shows that leadership with more care and concern for humanity tends to perform better in terms of generating results for OE. Therefore, both transformational and EL are based on individualized consideration for employees and are effective during COVID-19 in private and public sector organizations in Pakistan. Originality/value – The study has carried out the comparative analyses in three different ways, including leadership styles (transformational and ethical), type of organization (private and public) and time frames (pre and during COVID-19), which is a true contribution of the research in the Pakistani context